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Ch. 13 - Alcohols, Ethers and Related Compounds: Substitution and Elimination
Mullins - Organic Chemistry: A Learner Centered Approach 1st Edition
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471Not the one you use?Change textbook
Chapter 12, Problem 52a

Predict the product of the oxidation reactions shown.
(a) Chemical reaction showing isopropanol with H2CrO4 as oxidizing agent, arrow indicating reaction direction.

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1
Identify the type of oxidation reaction. Common oxidizing agents in organic chemistry include KMnO4, CrO3, PCC, and others. Determine which oxidizing agent is used in the reaction.
Determine the functional group present in the starting material. Common functional groups that undergo oxidation include alcohols, aldehydes, and ketones.
Apply the rules of oxidation for the specific functional group. For example, primary alcohols typically oxidize to aldehydes and then to carboxylic acids, while secondary alcohols oxidize to ketones.
Consider any structural changes that might occur during the oxidation process. This includes changes in the carbon skeleton or the formation of new functional groups.
Draw the structure of the predicted product, ensuring that all changes from the oxidation process are accurately represented. Verify that the product is consistent with the expected outcome based on the oxidizing agent and the starting material.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Oxidation Reaction

Oxidation in organic chemistry involves the increase in the oxidation state of a molecule, typically by adding oxygen or removing hydrogen. This process often converts alcohols to aldehydes, ketones, or carboxylic acids, depending on the type of alcohol and the oxidizing agent used.
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Functional Groups

Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. Understanding the functional group involved, such as alcohols, is crucial for predicting the outcome of oxidation reactions, as different groups react differently under oxidation conditions.
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Oxidizing Agents

Oxidizing agents are substances that facilitate oxidation by accepting electrons from other molecules. Common oxidizing agents in organic chemistry include potassium permanganate (KMnO4), chromic acid (H2CrO4), and PCC (pyridinium chlorochromate). The choice of oxidizing agent can influence the final product of the reaction.
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