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EAS:Ortho vs. Para Positions definitions
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Electrophilic Aromatic Substitution
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Electrophilic Aromatic Substitution
A reaction where an aromatic ring reacts with an electrophile, replacing a hydrogen atom on the ring.
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Ortho, Para major products
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Terms in this set (14)
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Electrophilic Aromatic Substitution
A reaction where an aromatic ring reacts with an electrophile, replacing a hydrogen atom on the ring.
Ortho Position
A location on a benzene ring adjacent to a substituent, offering two possible sites for substitution.
Para Position
A location on a benzene ring directly opposite a substituent, typically less sterically hindered.
Steric Hindrance
A spatial effect where bulky groups impede access to certain positions on a molecule, influencing product formation.
Electron Donating Group
A substituent that increases electron density on an aromatic ring, directing substitution to ortho and para positions.
Ortho-Para Director
A group that causes incoming substituents to add at ortho and para positions during aromatic substitution.
Sulfonation
A reaction introducing a sulfonic acid group onto an aromatic ring, often used to illustrate regioselectivity.
Nitration
A reaction adding a nitro group to an aromatic ring, commonly used to demonstrate directing effects.
Hydrogen Bonding
An interaction where a hydrogen atom forms a bridge between electronegative atoms, sometimes stabilizing ortho products.
Nitronium Ion
A reactive electrophile generated in nitration, responsible for attacking the aromatic ring.
Blocking Group
A substituent intentionally placed to prevent substitution at certain positions on an aromatic ring.
Product Ratio
The proportion of different isomers formed in a reaction, influenced by both position availability and steric effects.
Major Product
The most abundant compound formed in a reaction, often determined by steric and electronic factors.
Minor Product
A less prevalent compound formed in a reaction, typically due to less favorable conditions or positions.