4. Alkanes and Cycloalkanes

Give two names for each of the following alkyl halides and indicate whether each is primary, secondary, or tertiary:

c.

d.

For each of the following compounds,

1. give the IUPAC name.

2. give the common name (if possible).

3. classify the compound as a methyl, primary, secondary, or tertiary halide.

(a) (CH₃)₂CHCH₂Cl

Name the following alkanes and haloalkanes. When two or more substituents are present, list them in alphabetical order.

(b)

Name the following compounds:

b.

Draw all the isomers that have molecular formula C₅H₁₁Br. (Hint: There are eight.)

a. Give the systematic name for each of the isomers.

Draw the structure that corresponds with each name.

k. cyclobutylcyclohexane

l. cis-1-bromo-3-chlorocyclohexane

A student was given the structural formulas of several compounds and was asked to give them systematic names. How many did the student name correctly? Correct those that are misnamed.

e. 5-(2,2-dimethylethyl)nonane

f. isopentylbromide

Draw the structures and provide systematic names for parts a, b, and c by substituting a chlorine for a hydrogen of methylcyclohexane:

(c) three secondary alkyl halides

For each of the following compounds,

1. give the IUPAC name.

2. give the common name (if possible).

3. classify the compound as a methyl, primary, secondary, or tertiary halide.

b. (CH₃)₃CBr

Which of the following is the correct IUPAC name for a compound with a four-carbon chain, a bromine substituent on carbon $4$, and a ketone functional group on carbon $2$?

Give the structures of the following compounds.

a. methylene iodide

b. carbon tetrabromide

a. What is each compound’s systematic name?

b. Draw a skeletal structure for each condensed structure given and draw a condensed structure for each skeletal structure.

1. (CH₃)₃CCH₂CH₂CH₂CH(CH₃)₂

2.

Draw the structures of the following compounds.

a. sec-butyl chloride

b. isobutyl bromide

For each of the following compounds,

1. give the IUPAC name.

2. give the common name (if possible).

3. classify the compound as a methyl, primary, secondary, or tertiary halide.

e.

Draw the structure for each of the following:

c. sec-butyl iodide