4. Alkanes and Cycloalkanes

Draw a constitutional isomer for C₄H₁₁N containing a 1° amine at a

(a) 1° carbon,

(b) 2° carbon, and

(c) 3° carbon.

Give two names for each of the following alkyl halides and indicate whether each is primary, secondary, or tertiary:

a.

Which of the following is a secondary alkyl halide?

Draw all the isomers that have molecular formula C₅H₁₁Br. (Hint: There are eight.)

c. How many of the isomers are primary alkyl halides?

d. How many of the isomers are secondary alkyl halides?

e. How many of the isomers are tertiary alkyl halides?

Draw and name all five isomers of formula C₃H₅F.

Which of the following alkyl halides is a primary alkyl halide?

Which of the following compounds is not classified as a halide hydrocarbon?

Draw the structure for each of the following:

b. isopentyl fluoride

Which of the following alkyl halides is a tertiary alkyl halide?

Which of the following alkyl halides is a secondary alkyl halide?

Give the structures of the following compounds.

e. 2-bromo-3-ethyl-2-methylhexane

f. isobutyl bromide

Name the following compounds:

e.

f.

Give the structures of the following compounds.

g. cis-1-fluoro-3-(fluoromethyl)cyclohexane

h. tert-butyl chloride

What is the correct IUPAC name for the compound with the structure $\left(C_3{H}_7\right)C_3{H}_7)C_3{H}_{7}CBr$?

Draw the structures and provide systematic names for parts a, b, and c by substituting a chlorine for a hydrogen of methylcyclohexane:

(b) a tertiary alkyl halide