Show how you would accomplish the synthesis shown below.

Benzene reacts with ammonia and heat to form an acylated product.

Benzene reacts with bromine and iron bromide to yield an acylated product.

Benzene reacts with nitric and sulfuric acids, followed by iron and hydrochloric acid.

Benzene reacts with nitric and sulfuric acids, followed by iron and hydrochloric acid, to form a chlorinated product.