Pentoses also exist in a ring form, but they most commonly occur as furanose rings. D-Ribose exists in its furanose ring form in the nucleic acid RNA. Using the structure of D-ribose from Table 6.1, draw the furanose form of β-D-ribose.
Identify the following reactions as condensation or hydrolysis:
(a) two monosaccharides reacting to form a disaccharide
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Key Concepts
Condensation Reaction
Hydrolysis Reaction
Glycosidic Bond
Name the glycosidic bond present in mannobiose, shown in the following figure:
The sugar alcohol erythritol is often included in low-calorie sweeteners. It is 70% as sweet as table sugar. Erythritol is the reduced form of the aldotetrose erythrose. Draw erythritol.
Lactulose is a disaccharide used in the treatment of chronic constipation. Its formal name is galactose β(1→4) fructose.
(a) Draw the structure of lactulose.
For each of the following disaccharides, name the glycosidic bond and draw the monosaccharide units produced by hydrolysis:
(a)
The sugar alcohol ribitol is a component of the vitamin riboflavin and the energy transfer molecule FAD. Ribitol is formed when the monosaccharide ribose undergoes reduction at carbon 1. Draw the structure of ribitol.
