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Matter, Measurements, and Atomic Structure: General Chemistry Study Guide

Study Guide - Smart Notes

Tailored notes based on your materials, expanded with key definitions, examples, and context.

Matter and Its Classification

Definition and States of Matter

Matter is defined as anything that has mass and occupies space. It exists in three primary states: solid, liquid, and gas.

  • Solid: Has a definite shape and volume; particles are closely packed and vibrate in place.

  • Liquid: Has a definite volume but takes the shape of its container; particles are less tightly packed and can move past each other.

  • Gas: Has neither definite shape nor volume; particles are far apart and move freely.

Pure Substances and Mixtures

A pure substance has a fixed composition and distinct properties. Pure substances are classified as elements or compounds.

  • Element: A substance that cannot be broken down by chemical means. Examples: hydrogen (H), carbon (C).

  • Compound: A substance composed of two or more elements chemically combined in fixed proportions. Examples: water (H2O), carbon dioxide (CO2).

Mixtures are not mentioned directly, but for completeness: mixtures are combinations of two or more substances that retain their individual properties and can be separated by physical means.

Additional info: Mixtures can be homogeneous (uniform composition) or heterogeneous (non-uniform composition).

Atomic Structure and the Periodic Table

Atoms and Subatomic Particles

Atoms are the basic units of matter, composed of three main subatomic particles:

  • Protons: Positively charged particles located in the nucleus.

  • Neutrons: Neutral particles also located in the nucleus.

  • Electrons: Negatively charged particles that orbit the nucleus.

The Periodic Table

The periodic table organizes elements by their atomic number, which is the number of protons in the nucleus.

  • Atomic Number (Z): Defines the identity of an element.

  • Arrangement: Elements are arranged in rows (periods) and columns (groups) based on similar properties.

Chemical Bonds

Ionic and Covalent Bonds

Chemical bonds are forces that hold atoms together in compounds.

  • Ionic Bond: Formed when electrons are transferred from a metal to a nonmetal, resulting in oppositely charged ions that attract each other.

  • Covalent Bond: Formed when atoms share pairs of electrons, typically between nonmetals.

Example: Sodium chloride (NaCl) is an ionic compound; water (H2O) is a covalent compound.

Measurement and SI Units

SI Units

The International System of Units (SI) is used for scientific measurements.

  • Meter (m): Unit of length

  • Kilogram (kg): Unit of mass

  • Second (s): Unit of time

  • Kelvin (K): Unit of temperature

  • Mole (mol): Unit for amount of substance

Significant Figures

Significant figures indicate the precision of a measurement. The number of significant digits reflects the certainty in the measured value.

  • Rules: All nonzero digits are significant; zeros between nonzero digits are significant; leading zeros are not significant; trailing zeros in a decimal number are significant.

Density

Density is a physical property defined as mass per unit volume.

  • Formula:

  • Where: d is density, m is mass, V is volume.

  • Units: Commonly expressed in g/cm3 or kg/m3.

  • Example: If a sample has a mass of 10 g and a volume of 2 cm3, its density is .

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