BackMatter and Measurements: Foundations of General Chemistry
Study Guide - Smart Notes
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Classification of Matter
Types of Matter
Chemistry is the study of matter and the changes it undergoes. Matter is anything that occupies space and has mass. It can be classified into three main types:
Element: The simplest type of matter, composed of only one kind of atom. Examples include gold (Au) and oxygen (O2).
Compound: Matter composed of two or more different elements that are chemically bonded together, such as water (H2O).
Mixture: Matter composed of elements and/or compounds that are physically mixed together, such as air or salad.
Pure substances include elements and compounds, while mixtures can be homogeneous (uniform composition, e.g., saltwater) or heterogeneous (non-uniform, e.g., salad).
Practice and Examples
Compounds can only be broken down by chemical means.
Milk is an example of a heterogeneous mixture.
Gold bar is an element; ammonia (NH3) is a compound; orange juice and wine are mixtures.
Physical and Chemical Changes
Physical Changes
Physical changes alter the state or appearance of matter without changing its composition. Examples include melting, freezing, dissolving, and tearing.
Example: Dissolving sugar in water is a physical change.
Chemical Changes
Chemical changes result in the formation of new substances with different properties. This involves making or breaking chemical bonds.
Example: Iron rusting or wood burning are chemical changes.
Reversible vs. Irreversible Changes
Reversible changes: Can be undone (e.g., melting and freezing).
Irreversible changes: Cannot be undone (e.g., burning, cooking).
Chemical and Physical Properties
Chemical Properties
Chemical properties describe a substance's ability to undergo chemical changes, forming new substances. Examples include flammability, reactivity with acids, and radioactivity.

Physical Properties
Physical properties can be observed or measured without changing the substance's chemical identity. Examples include color, mass, density, melting point, and state of matter.
Example: Mercury is a silvery liquid at 25ºC (physical property).
Intensive vs. Extensive Properties
Intensive Properties
Intensive properties do not depend on the amount of substance present. They are useful for identifying substances.
Examples: Density, melting point, color, luster.
Extensive Properties
Extensive properties depend on the amount of substance present.
Examples: Mass, volume, energy.
Temperature and Heat
Thermal Energy, Temperature, and Heat
Thermal energy: Total kinetic and potential energy of particles in a substance.
Temperature: Average kinetic energy of particles; measured in Celsius (ºC), Fahrenheit (ºF), or Kelvin (K).
Heat: Transfer of thermal energy from a hotter object to a cooler one.
Temperature Conversions
Scientific Notation
Format and Conversion
Scientific notation expresses numbers as , where and is an integer.
Positive exponents indicate large numbers; negative exponents indicate small numbers.
SI Units and Metric Prefixes
SI Base Units
Mass: kilogram (kg)
Length: meter (m)
Time: second (s)
Temperature: kelvin (K)
Amount of substance: mole (mol)
Electric current: ampere (A)
Luminous intensity: candela (cd)
Metric Prefixes
kilo- (), centi- (), milli- (), micro- (), nano- (), etc.
Significant Figures
Rules for Counting Significant Figures
All nonzero digits are significant.
Zeros between nonzero digits are significant.
Leading zeros are not significant.
Trailing zeros are significant if there is a decimal point.
Significant Figures in Calculations
Multiplication/Division: Result has the same number of significant figures as the value with the fewest significant figures.
Addition/Subtraction: Result has the same number of decimal places as the value with the fewest decimal places.
Conversion Factors and Dimensional Analysis
Conversion Factors
Conversion factors are ratios that relate different units and are used to convert from one unit to another.
Example:
Dimensional Analysis
Dimensional analysis is a systematic approach to problem-solving that uses conversion factors to move from one unit to another.
Set up the problem so that units cancel appropriately, leaving the desired unit.
Density
Definition and Formula
Density is the amount of mass per unit volume. It is a useful property for identifying substances and solving problems involving mass and volume.
Units
Solids/Liquids: g/cm3 or kg/L
Gases: g/L
Water Displacement
Water displacement is used to determine the volume of irregularly shaped objects by measuring the change in water level when the object is submerged.
Geometric and Non-Geometric Objects
Volume Formulas
Cube:
Sphere:
Cylinder:
Application
Given the mass and volume (or dimensions), density can be calculated for both geometric and non-geometric objects.