BackIntroduction to General Chemistry: Matter, Properties, and Measurement
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Introduction to General Chemistry
Matter and Its Classification
Chemistry is the study of matter, its properties, and the changes it undergoes. Matter is anything that occupies space and has mass. It can be classified based on its physical state and composition.
Physical State: Solid, liquid, or gas.
Composition: Elements, compounds, or mixtures.
Type | Definition/Example | Symbol |
|---|---|---|
Element | Pure substance made of a single type of atom | H, O, Na |
Compound | Pure substance made of two or more elements chemically combined | H2O, CO2 |
Mixture | Physical combination of two or more substances | Air, saltwater |
Physical and Chemical Changes
Physical Changes
Physical changes alter the appearance or state of a substance without changing its composition.
Examples: Melting, freezing, dissolving, breaking
Chemical Changes
Chemical changes (chemical reactions) result in the formation of new substances with different properties.
Examples: Burning, rusting, digestion
Phase Changes: Reversible and Irreversible
Reversible Changes
Reversible changes can be undone, such as phase changes between solid, liquid, and gas (melting, freezing, boiling).
Irreversible Changes
Irreversible changes cannot be undone by simple physical means (e.g., burning paper).
Phase Change | Solid → Liquid | Liquid → Gas | Solid → Gas |
|---|---|---|---|
Name | Melting | Boiling | Sublimation |
Chemical and Physical Properties
Chemical Properties
Chemical properties describe a substance's ability to undergo chemical changes (e.g., flammability, reactivity).
Physical Properties
Physical properties can be observed without changing the substance's identity (e.g., color, melting point, density).
Intensive vs. Extensive Properties
Intensive Properties
Do not depend on the amount of substance (e.g., density, boiling point).
Extensive Properties
Depend on the amount of substance (e.g., mass, volume).
Property Type | Examples |
|---|---|
Intensive | Density, melting point |
Extensive | Mass, volume, length |
SI Units and Measurements
SI Base Units
The International System of Units (SI) is used for scientific measurements.
Physical Quantity | Name | Symbol |
|---|---|---|
Length | meter | m |
Mass | kilogram | kg |
Time | second | s |
Temperature | kelvin | K |
Amount of substance | mole | mol |
Electric current | ampere | A |
Luminous intensity | candela | cd |
Derived Units, Area, and Volume
Area:
Volume:
Metric Prefixes
Metric Prefix Multipliers
Prefix | Symbol | Multiplier |
|---|---|---|
kilo | k | |
centi | c | |
milli | m | |
micro | μ | |
nano | n |
Temperature and Scientific Notation
Temperature Scales
Scale | Conversion Formula |
|---|---|
Celsius to Kelvin | |
Celsius to Fahrenheit |
Scientific Notation
Expresses numbers as a coefficient times a power of ten (e.g., ).
Significant Figures
Rules for Significant Figures
Nonzero numbers are always significant.
Zeros between nonzero digits are significant.
Leading zeros are not significant.
Trailing zeros are significant only if there is a decimal point.
Significant Figures in Calculations
Addition/Subtraction: Result has the same number of decimal places as the measurement with the fewest decimal places.
Multiplication/Division: Result has the same number of significant figures as the measurement with the fewest significant figures.
Conversion Factors and Dimensional Analysis
Conversion Factors
Conversion factors are ratios used to express the same quantity in different units.
Quantity | Equivalent | Factor |
|---|---|---|
Length | 1 km = 1000 m | 1000 |
Mass | 1 kg = 1000 g | 1000 |
Dimensional analysis is a method for converting units using conversion factors.
Density and Measurement
Density
Density is the ratio of mass to volume.
Formula:
Density of Common Objects
Objects with density less than water float; those with greater density sink.
Density in Water Displacement
Density can be measured by water displacement: Submerge an object in water and measure the volume of water displaced to find the object's volume.
Example: If a metal block has a mass of 50 g and displaces 20 mL of water, its density is .