BackIntroduction to General Chemistry: Matter, Properties, and Measurement
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Introduction to General Chemistry
Matter and Its Classification
Chemistry is the study of matter, its properties, and the changes it undergoes. Matter is anything that occupies space and has mass. It can be classified based on its physical state and composition.
Matter: Anything that has mass and occupies space.
Classification by State: Solid, liquid, gas.
Classification by Composition: Element, compound, mixture.
State | Arrangement of Particles | Shape/Volume | Example |
|---|---|---|---|
Solid | Particles close together in fixed, rigid structure | Definite shape and volume | Ice |
Liquid | Particles close but can move past each other | Definite volume, no definite shape | Water |
Gas | Particles far apart, move freely | No definite shape or volume | Oxygen (O2) |
Physical and Chemical Changes
Physical Changes
Physical changes alter the appearance or state of a substance without changing its composition.
Examples: Melting, freezing, boiling, dissolving
Chemical Changes
Chemical changes (chemical reactions) result in the formation of new substances with different properties.
Examples: Rusting of iron, burning of wood
Phase Changes: Reversible and Irreversible
Reversible Changes
Reversible changes can be undone, such as melting and freezing.
Irreversible Changes
Irreversible changes cannot be undone by simple physical means, such as burning or digestion.
Phase Change | Reversible | Irreversible |
|---|---|---|
Melting/Freezing | Yes | No |
Burning | No | Yes |
Chemical and Physical Properties
Chemical Properties
Chemical properties describe a substance's ability to undergo chemical changes, forming new substances.
Example: Flammability, reactivity with acid
Physical Properties
Physical properties can be observed or measured without changing the substance's composition.
Example: Color, melting point, density
Intensive vs. Extensive Properties
Intensive Properties
Intensive properties do not depend on the amount of substance present.
Examples: Density, boiling point, color
Extensive Properties
Extensive properties depend on the amount of substance present.
Examples: Mass, volume, length
Property Type | Examples |
|---|---|
Intensive | Density, melting point |
Extensive | Mass, volume, length |
SI Units and Measurements
SI Base Units
The International System of Units (SI) is used for scientific measurements. Each physical quantity has a standard unit.
Physical Quantity | Name | Symbol |
|---|---|---|
Length | meter | m |
Mass | kilogram | kg |
Time | second | s |
Temperature | kelvin | K |
Amount of substance | mole | mol |
Electric current | ampere | A |
Luminous intensity | candela | cd |
Metric Prefixes
Metric prefixes indicate multiples or fractions of units.
Prefix | Symbol | Multiplier |
|---|---|---|
kilo | k | 103 |
centi | c | 10-2 |
milli | m | 10-3 |
micro | μ | 10-6 |
nano | n | 10-9 |
Temperature and Scientific Notation
Temperature Scales
Temperature can be measured in Celsius, Kelvin, or Fahrenheit. The Kelvin scale is the SI unit for temperature.
Scale | Conversion Formula |
|---|---|
Celsius to Kelvin |
Scientific Notation
Scientific notation expresses numbers as a multiple of a power of ten, making it easier to handle very large or small values.
General form:
Significant Figures
Rules for Significant Figures
Nonzero digits are always significant.
Any zeros between significant digits are significant.
Leading zeros are not significant.
Trailing zeros are significant only if there is a decimal point.
Significant Figures in Calculations
Multiplication/Division: Result has the same number of significant figures as the measurement with the fewest significant figures.
Addition/Subtraction: Result has the same number of decimal places as the measurement with the fewest decimal places.
Conversion Factors and Dimensional Analysis
Conversion Factors
Conversion factors are ratios used to express a quantity in different units.
Quantity | Conversion | Factor |
|---|---|---|
Length | 1 km = 1000 m | 1 km / 1000 m |
Mass | 1 kg = 1000 g | 1 kg / 1000 g |
Dimensional Analysis
Dimensional analysis is a method for converting units using conversion factors.
Example: To convert 5 km to meters:
Density and Measurement
Density
Density is the mass per unit volume of a substance.
Formula:
Density of Common Objects
Objects with density less than water float; those with greater density sink.
Density in Water Displacement
Density can be measured by water displacement, especially for irregular solids. The volume of water displaced equals the volume of the object.
Example: If a solid displaces 10 mL of water and has a mass of 25 g, its density is