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General Chemistry: Matter, Properties, Measurements, and Calculations

Study Guide - Smart Notes

Tailored notes based on your materials, expanded with key definitions, examples, and context.

Classification of Matter

Types of Matter

Chemistry is the study of matter and the changes it undergoes. Matter is anything that occupies space and has mass. It can be classified into three main types:

  • Element: The simplest type of matter, composed of one kind of atom. Examples include gold (Au) and oxygen (O2).

  • Compound: Matter composed of two or more different elements that are chemically bonded together, such as water (H2O).

  • Mixture: Matter composed of elements and/or compounds that are physically mixed together, such as air or salad.

Pure substances include elements and compounds, while mixtures can be homogeneous (uniform composition, e.g., saltwater) or heterogeneous (non-uniform, e.g., salad).

Physical and Chemical Changes

Physical Changes

Physical changes alter the state or appearance of matter without changing its composition. Examples include melting, freezing, dissolving, and tearing.

  • Example: Dissolving sugar in water is a physical change because the sugar can be recovered by evaporation.

Chemical Changes

Chemical changes result in the formation of new substances with different properties. These changes involve making or breaking chemical bonds.

  • Example: Burning wood or rusting iron are chemical changes.

Reversible vs. Irreversible Changes

  • Reversible changes: Can be undone, such as melting and freezing.

  • Irreversible changes: Cannot be undone, such as burning or cooking.

Chemical and Physical Properties

Chemical Properties

Chemical properties describe how a substance reacts with other substances, resulting in a change in composition.

  • Examples: Flammability, reactivity with acids, toxicity, radioactivity.

Examples of chemical properties

Physical Properties

Physical properties can be observed or measured without changing the substance's chemical identity. These include color, mass, density, melting point, and boiling point.

  • Examples: Color, mass, hardness, luster, state of matter.

Color as a physical propertyMass as a physical propertyShape as a physical propertyLuster as a physical property

Intensive vs. Extensive Properties

Intensive Properties

Intensive properties do not depend on the amount of substance present. They are useful for identifying substances.

  • Examples: Density, color, boiling point, luster.

Examples of intensive propertiesExamples of intensive properties

Extensive Properties

Extensive properties depend on the amount of substance present. They are additive for the same substance.

  • Examples: Mass, volume, length, total charge.

Examples of extensive propertiesExamples of extensive properties

Temperature and Heat

Thermal Energy, Temperature, and Heat

Thermal energy is the total kinetic and potential energy of all atoms in an object. Temperature is the average kinetic energy of particles, while heat is the transfer of thermal energy from a hotter object to a cooler one.

  • Temperature units: Celsius (ºC), Fahrenheit (ºF), Kelvin (K).

Thermometer showing temperature

Temperature Conversions

Scientific Notation

Format and Use

Scientific notation expresses very large or small numbers in the form , where and is an integer.

  • Positive exponent: Move decimal to the right.

  • Negative exponent: Move decimal to the left.

SI Units and Metric Prefixes

SI Base Units

The International System of Units (SI) uses seven base units for physical quantities:

Physical Quantity

Name

Symbol

Mass

kilogram

kg

Length

meter

m

Time

second

s

Temperature

kelvin

K

Amount of substance

mole

mol

Electric current

ampere

A

Luminous intensity

candela

cd

SI base units

Metric Prefixes

Metric prefixes indicate multiples or fractions of base units. For example, kilo- (k) means 1,000 times the base unit, and milli- (m) means one-thousandth.

  • Examples: 1 km = 1,000 m; 1 mg = 0.001 g

Significant Figures

Rules for Counting Significant Figures

  • All nonzero digits are significant.

  • Zeros between nonzero digits are significant.

  • Leading zeros are not significant.

  • Trailing zeros in a decimal number are significant.

  • Exact numbers have an infinite number of significant figures.

Significant Figures in Calculations

  • Multiplication/Division: The result has as many significant figures as the value with the fewest significant figures.

  • Addition/Subtraction: The result has as many decimal places as the value with the fewest decimal places.

Conversion Factors and Dimensional Analysis

Conversion Factors

A conversion factor is a ratio that expresses how many of one unit are equal to another unit. For example, 1 inch = 2.54 cm.

Dimensional Analysis

Dimensional analysis is a systematic approach to problem-solving that uses conversion factors to move from one unit to another.

  • Set up the problem so that units cancel appropriately, leaving only the desired unit.

Density

Definition and Formula

Density is the amount of mass per unit volume. It is a physical property that can be used to identify substances.

  • Formula:

Units

  • Solids/Liquids: g/cm3 or kg/L

  • Gases: g/L

Density of Geometric and Non-Geometric Objects

  • For regular shapes, use geometric formulas to find volume.

  • For irregular shapes, use water displacement to find volume.

Water displacement method

Summary Table: Classification of Matter

Type

Composition

Separable?

Examples

Element

One kind of atom

No

Gold, Oxygen

Compound

Two or more elements, chemically bonded

Yes (chemical)

Water, Carbon dioxide

Mixture

Two or more substances, physically mixed

Yes (physical)

Air, Salad

Additional info: This guide covers the foundational concepts of matter, properties, measurements, and calculations essential for success in general chemistry. Practice problems and examples are included to reinforce understanding.

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