BackFundamentals of Atomic Structure and Chemical Bonding
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Atoms and Subatomic Particles:
An atom is the smallest unit of an element, consisting of a nucleus (containing protons and neutrons) and electrons orbiting the nucleus.
Protons have a positive charge, neutrons have no charge, and electrons have a negative charge.
Atomic Number and Mass:
The atomic number is the number of protons in an atom and determines the element.
Atomic mass is the sum of protons and neutrons.
Number of neutrons = atomic bsp;mass − atomic bsp;number
Electron Configuration and Energy Levels:
Electrons occupy energy levels (shells) around the nucleus.
The first energy level holds up to 2 electrons, the second up to 8, and the third up to 18.
Stable electron configurations occur when energy levels are filled according to the element's number of electrons.
Ions and Isotopes:
Ions are atoms with a net charge due to loss or gain of electrons (protons do not change).
Isotopes are atoms of the same element with different numbers of neutrons (e.g., Carbon-12, Carbon-13, Carbon-14).
Elements, Compounds, and Molecules:
An element is a pure substance made of one type of atom.
A compound is formed when two or more different elements bond together (e.g., NaCl, H2O).
A molecule is a group of atoms held together by covalent bonds (e.g., O2).
Chemical Bonds:
Covalent bonds: Atoms share electrons; can be polar (unequal sharing, e.g., H2O) or nonpolar (equal sharing, e.g., H2).
Ionic bonds: Formed when atoms transfer electrons, resulting in oppositely charged ions that attract (e.g., Na+ + Cl- → NaCl).
Hydrogen bonds: Weak attractions between a hydrogen atom in one molecule and an electronegative atom in another (important in water and biological molecules).
Properties of Water:
Water is polar, allowing it to form hydrogen bonds.
Exhibits cohesion (attraction between water molecules) and adhesion (attraction to other substances), leading to phenomena like meniscus and capillary action.
High specific heat capacity and acts as a versatile solvent.
Solutions and pH:
A solution consists of a solute (substance dissolved) and a solvent (substance doing the dissolving; water is a common solvent).
pH measures the concentration of hydrogen ions (H+) versus hydroxide ions (OH-) in a solution, ranging from 0 (acidic) to 14 (basic), with 7 being neutral.
Chemical Equations:
Represent chemical reactions, showing reactants and products.
Coefficients indicate the number of molecules; subscripts indicate the number of atoms in a molecule.
Example: 6CO2 + 6H2O → 6O2 + 6H2O + energy