BackFundamental Concepts in General Chemistry: Atoms, Elements, Bonds, and Water
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Atoms and Subatomic Particles:
An atom is the smallest unit of an element, consisting of a nucleus (containing protons and neutrons) and electrons orbiting in energy levels.
Protons have a positive charge, neutrons have no charge, and electrons have a negative charge.
Energy Levels and Electron Configuration:
Electrons occupy specific energy levels around the nucleus; each level holds a set number of electrons (first: 2, second: 8, third: 18).
Stable electron configurations are achieved when energy levels are filled according to the element's total electrons.
Elements and the Periodic Table:
Elements are pure substances that cannot be broken down further; each has a unique atomic number (number of protons).
Atomic mass is the sum of protons and neutrons.
Only a subset of elements are essential for life, with C, H, N, and O making up most of human mass.
Isotopes and Ions:
Isotopes are atoms of the same element with different numbers of neutrons.
Ions are charged atoms formed by gaining or losing electrons; protons remain unchanged.
Chemical Bonds:
Covalent Bonds: Atoms share electrons; can be polar (unequal sharing, e.g., H2O) or nonpolar (equal sharing, e.g., H2).
Ionic Bonds: Formed when atoms transfer electrons, resulting in oppositely charged ions (e.g., Na+ + Cl- → NaCl).
Hydrogen Bonds: Weak attractions between a hydrogen atom and an electronegative atom, important in water and biological molecules.
Properties of Water:
Water is polar, allowing it to form hydrogen bonds, leading to high cohesion, adhesion, high specific heat, and its role as a versatile solvent.
Cohesion and adhesion explain phenomena like surface tension and capillary action.
Water's high specific heat helps regulate temperature; evaporative cooling (e.g., sweating) is a result.
Solutions and pH:
Solutions consist of a solute (substance dissolved) and a solvent (substance doing the dissolving, often water).
pH measures the concentration of hydrogen ions (H+) versus hydroxide ions (OH-), ranging from 0 (acidic) to 14 (basic), with 7 being neutral.
Acids increase H+ concentration; bases increase OH- concentration.
Chemical Equations:
Chemical reactions are represented by equations showing reactants and products.
Coefficients indicate the number of molecules; subscripts indicate the number of atoms in a molecule.
Example equation (photosynthesis): 6CO2+6H2O→C6H12O6+6O2