BackBasic Chemistry Concepts for General Chemistry
Study Guide - Smart Notes
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Atoms and Atomic Structure
Definition and Arrangement
An atom is the smallest particle of an element that retains the properties of that element. Atoms are composed of subatomic particles arranged in a specific structure.
Nucleus: The central part of the atom containing protons and neutrons.
Proton: A positively charged particle found inside the nucleus.
Neutron: A particle found in the nucleus with no charge (neutral).
Electron: A negatively charged particle that orbits the nucleus in energy levels.
Example: The carbon atom has 6 protons, 6 neutrons, and 6 electrons.
Energy Levels
Electrons travel around the nucleus in regions called energy levels or shells. Each energy level can hold a specific maximum number of electrons:
First energy level: can hold up to 2 electrons
Second energy level: can hold up to 8 electrons
Third energy level: can hold up to 18 electrons
All energy levels being used must be full for an atom to be stable.
Example: An atom with 8 electrons will have 2 in the first level and 6 in the second level.
Electron Configuration Examples
Atom with 10 electrons: 2 in the first level, 8 in the second level (stable configuration).
Atom with 16 electrons: 2 in the first level, 8 in the second, 6 in the third (not fully stable).
Elements and the Periodic Table
Definition and Properties
An element is a substance that cannot be broken down into simpler substances by chemical means. There are 90 naturally occurring elements, all listed on the Periodic Table.
Only 25 elements are essential for living things.
96% of the mass of a human is composed of carbon (C), hydrogen (H), nitrogen (N), and oxygen (O).
Atomic Number and Atomic Mass
Atomic Number: The number of protons in the nucleus of an atom. It is also equal to the number of electrons in a neutral atom.
Atomic Mass: The sum of protons and neutrons in the nucleus.
Formula:
Example: Carbon has atomic number 6 and atomic mass 12, so it has 6 neutrons.
Ions and Isotopes
Ions
Ions are charged particles formed when atoms gain or lose electrons. The number of protons does not change.
Cation: Positively charged ion (loss of electrons).
Anion: Negatively charged ion (gain of electrons).
Example: has 11 protons and 10 electrons.
Isotopes
Isotopes are atoms of the same element with different numbers of neutrons.
Carbon-12: 6 protons, 6 neutrons
Carbon-13: 6 protons, 7 neutrons
Carbon-14: 6 protons, 8 neutrons
How Elements Combine: Compounds and Molecules
Compounds
A compound is a substance made of two or more different elements bonded together.
Example: Sodium chloride (NaCl), Water (H2O)
Molecules
A molecule is a group of atoms held together by covalent bonds.
Example: Oxygen molecule (O2)
Chemical Bonds
Covalent Bonds
Covalent bonds form when two atoms share electrons. These are common in organic compounds.
Example: Water (H2O)
Polar and Nonpolar Bonds
Polar Bond: Electrons are not shared equally, resulting in partial charges on atoms. Example: Water (H2O)
Nonpolar Bond: Electrons are shared equally. Example: Hydrogen gas (H2), Ethane (C2H6)
Ionic Bonds
Ionic bonds form when atoms transfer electrons, resulting in oppositely charged ions that attract each other.
Example:
Hydrogen Bonds
Hydrogen bonds are weak attractions between a hydrogen atom in one molecule and an electronegative atom (like oxygen) in another molecule. These bonds are important for holding water molecules and large biological molecules together.
Example: Hydrogen bonds between water molecules
Properties of Water
Polarity
Water is a polar molecule due to the uneven distribution of charge. Oxygen has a stronger pull on electrons than hydrogen, making the oxygen side slightly negative and the hydrogen side slightly positive.
Cohesion and Adhesion
Cohesion: Attraction between molecules of the same substance (water molecules stick together).
Adhesion: Attraction between molecules of different substances (water sticks to glass, causing a meniscus and capillary action).
High Specific Heat Capacity
Water can absorb large amounts of heat due to its many hydrogen bonds, helping regulate temperature in organisms and environments.
Evaporative Cooling
As water evaporates, it removes heat, cooling surfaces (e.g., sweating).
Versatile Solvent
Water dissolves many substances due to its polarity, making it an excellent solvent in biological systems.
Solutions, Acids, and Bases
Solutions
A solution consists of a solute (substance dissolved) and a solvent (substance doing the dissolving). Water is often the solvent in biological systems.
Example: Iced tea mix (solute) dissolved in water (solvent)
pH Scale
The pH scale measures the concentration of hydrogen ions (H+) versus hydroxide ions (OH-) in a solution. The scale ranges from 0 (acidic) to 14 (basic), with 7 being neutral.
Acid: More H+ ions, pH below 7 (e.g., soda, pH 3)
Base: More OH- ions, pH above 7 (e.g., Nair, pH 13)
Neutral: Equal H+ and OH- ions (pure water, pH 7)
Chemical Equations
Reactants and Products
Chemical equations show how substances (reactants) combine to form new substances (products).
Example:
Reactants: Substances that start the reaction
Products: Substances formed by the reaction
Coefficients and Subscripts
Coefficients: Numbers before elements/compounds indicating how many molecules are involved (e.g., 6CO2 means 6 molecules of CO2).
Subscripts: Numbers within chemical formulas indicating the number of atoms in a molecule (e.g., O2 means 2 oxygen atoms).
Summary Table: Atomic Particles
Particle | Charge | Location |
|---|---|---|
Proton | +1 | Nucleus |
Neutron | 0 | Nucleus |
Electron | -1 | Energy levels (orbitals) |
Summary Table: Types of Chemical Bonds
Bond Type | Description | Example |
|---|---|---|
Covalent | Atoms share electrons | H2O |
Ionic | Atoms transfer electrons, forming ions | NaCl |
Hydrogen | Weak attraction between molecules | Between water molecules |
Additional info: Some context and examples have been expanded for clarity and completeness.