Textbook Question
Draw the structure that corresponds to the name provided.
(a) (1R,5S)-5-methylcyclohex-3-enol
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Ch. 13 - Alcohols, Ethers and Related Compounds: Substitution and Elimination
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471
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Table of contents
- Ch. 2 - General Chemistry Translated: Finding the Electrons114
- Ch. 3 - Alkanes and Cycloalkanes: Properties and Conformational Analysis109
- Ch. 4 - Acids and Bases: Electron Flow144
- Ch. 5 - Chemical Reaction Analysis: Thermodynamics and Kinetics118
- Ch. 6 - Stereoisomerism: Arrangement of Atoms in Space112
- Ch. 7 - Principles of Green (Organic) Chemistry3
- Ch. 8 - Alkenes I: Properties and Electrophilic Additions158
- Ch. 9 - Alkenes II: Oxidation and Reduction150
- Ch. 10 - Alkynes: Electrophilic Addition and Redox Reactions101
- Ch. 11 - Properties and Synthesis of Alkyl Halides: Radical Reactions108
- Ch. 12 - Substitution and Elimination: Reactions of Haloalkanes172
- Ch. 13 - Alcohols, Ethers and Related Compounds: Substitution and Elimination239
- Ch. 14 - Structural Identification I: Infrared Spectroscopy and Mass Spectrometry54
- Ch. 15 - Structural Identification II: Nuclear Magnetic Resonance Spectroscopy93
- Ch. 16 - Metals in Organic Chemistry48
- Ch. 17 - Carbonyl Addition Reactions: Aldehydes and Ketones45
- Ch. 18 - Nucleophilic Acyl Substitution I: Carboxylic Acids18
- Ch. 19 - Nucleophilic Acyl Substitution II: Carboxylic Acid Derivatives39
- Ch. 20 - Enolates: Carbonyl Addition and Substitution13
- Ch. 21 - Conjugated Systems I: Stability and Addition Reactions56
- Ch. 22 - Conjugated Systems II: Pericyclic Reactions54
- Ch. 23 - Benzene I: Aromatic Stability and Substitution Reactions64
- Ch. 24 - Benzene II: Reactions Influenced by the Aromatic Ring62
- Ch. 25 - Amines: Structure, Reactions, and Synthesis27
- Ch. 26 - Amino Acids, Proteins, and Peptide Synthesis9
- Ch. 27 - Carbohydrates, Nucleic Acids, and Lipids54
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471Not the one you use?Change textbook
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Mullins 1st EditionCh. 13 - Alcohols, Ethers and Related Compounds: Substitution and EliminationProblem 6f
Mullins 1st EditionCh. 13 - Alcohols, Ethers and Related Compounds: Substitution and EliminationProblem 6fChapter 12, Problem 6f
Provide the IUPAC name for the following molecules.
(f) 
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Identify the longest continuous carbon chain in the molecule. This chain will determine the base name of the compound according to the number of carbon atoms it contains.
Number the carbon atoms in the longest chain starting from the end nearest to the first point of branching or the highest priority functional group.
Identify and name any substituents (alkyl groups, halogens, etc.) attached to the main chain. Use prefixes like 'methyl-', 'ethyl-', 'chloro-', etc., based on the type of substituent.
Assign a locant (position number) to each substituent based on its position on the main chain. Ensure that the numbers are as low as possible.
Combine the names of the substituents with the base name of the compound, arranging substituents alphabetically and using hyphens to separate numbers from names. Use commas to separate multiple locants for identical substituents.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
IUPAC Nomenclature
IUPAC nomenclature is a standardized system for naming chemical compounds. It ensures that each compound has a unique name that describes its structure. The system uses specific rules to identify the longest carbon chain, functional groups, and substituents, assigning prefixes, infixes, and suffixes accordingly.
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The different parts of an IUPAC name
Functional Groups
Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. Identifying functional groups such as alcohols, ketones, or carboxylic acids is crucial in determining the IUPAC name, as they influence the suffix and priority in naming.
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Carbon Chain Identification
Identifying the longest continuous carbon chain in a molecule is a fundamental step in IUPAC nomenclature. This chain serves as the base name of the compound, and its length determines the root name (e.g., methane, ethane, propane). Substituents and functional groups are then named and numbered based on their position relative to this main chain.
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Related Practice
Textbook Question
Provide the IUPAC name for the following molecules.
(a)
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Textbook Question
The mechanism of the acid-catalyzed hydration of an alkene to make an alcohol is shown. If this reaction is reversible, draw a mechanism that justifies formation of the alkene from the alcohol under similar conditions. How do you know this mechanism is correct?
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Textbook Question
Draw the structure that corresponds to the name provided.
(c) (2E,4S,6Z)-octa-2,6-dien-4-ol
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Textbook Question
Provide the IUPAC name for the following molecules.
(b)
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Textbook Question
Draw the structure that corresponds to the name provided.
(b) (2R,3R,4S)-heptane-2,3,4-triol