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Gibbs Free Energy definitions
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Gibbs Free Energy
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Gibbs Free Energy
Predicts reaction favorability by combining enthalpy, entropy, and temperature; negative values indicate spontaneous processes.
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Terms in this set (15)
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Gibbs Free Energy
Predicts reaction favorability by combining enthalpy, entropy, and temperature; negative values indicate spontaneous processes.
Enthalpy
Represents the sum of bond association energies; negative values indicate bond formation, positive values indicate bond breaking.
Entropy
Measures system disorder; positive values favor increased randomness, while negative values indicate increased order.
Exothermic Reaction
Process where energy is released due to bond formation, resulting in a negative enthalpy change.
Endothermic Reaction
Process where energy is absorbed due to bond breaking, resulting in a positive enthalpy change.
Temperature
Amplifies the effect of entropy on reaction favorability; higher values make disorder more influential.
Transition State
High-energy, transient configuration at the peak of a reaction coordinate; cannot be isolated in a test tube.
Intermediate
Higher-energy species between reactants and products that can be isolated and observed.
Free Energy Diagram
Graphical representation showing energy changes during a reaction, highlighting transition states and intermediates.
Activation Energy
Minimum energy required to reach a transition state from reactants; determines the reaction rate.
Rate-Determining Step
Step with the highest activation energy in a multi-step reaction, controlling the overall reaction speed.
Spontaneity
Describes whether a reaction proceeds without external input, closely linked to negative Gibbs free energy.
Exergonic Reaction
Process with a negative Gibbs free energy, indicating a thermodynamically favored reaction.
Endergonic Reaction
Process with a positive Gibbs free energy, indicating a non-favored reaction under standard conditions.
Bond Association Energy
Energy required to break or form chemical bonds, contributing to the overall enthalpy change.