Name four important monosaccharides and tell where each occurs in nature.
How many chiral carbon atoms are present in each of the molecules shown in Problem 20.31?
a. 
b. 
c. 
d. 
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Key Concepts
Chirality
Chiral Carbon Atom
Stereochemistry
Only three stereoisomers are possible for 2,3-dibromo-2, 3-dichlorobutane. Draw them, indicating which pair are enantiomers (optical isomers). Why does the other isomer not have an enantiomer?
Classify the four carbohydrates (a)–(d) by indicating the nature of the carbonyl group and the number of carbon atoms present. For example, glucose is an aldohexose.
c.
Draw the open-chain structure of a 4-carbon deoxy sugar.
Classify the four carbohydrates (a)–(d) by indicating the nature of the carbonyl group and the number of carbon atoms present. For example, glucose is an aldohexose.
d.
In solution, glucose exists predominantly in the cyclic hemiacetal form, which does not contain an aldehyde group. How is it possible for mild oxidizing agents to oxidize glucose?
