D-Fructose can form a six-membered cyclic hemiacetal as well as the more prevalent five-membered cyclic form. Draw the α isomer of D-fructose in the six-membered ring.
How are amylose and amylopectin similar to each other, and how are they different from each other?
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Amylose
Amylopectin
Starch Structure and Function
Are the α and β forms of the disaccharide lactose enantiomers of each other? Why or why not?
Amylose (a form of starch) and cellulose are both polymers of glucose. What is the main structural difference between them? What roles do these two polymers have in nature?
Trehalose, a disaccharide found in the blood of insects, has the following structure. What simple sugars would you obtain on hydrolysis of trehalose? (Hint: Rotate one of the rings in your head or redraw it rotated.)
Draw a disaccharide of two cyclic mannose molecules attached by an α-1,4 glycosidic linkage. Explain why the glycosidic products in Problem 20.58 are not reducing sugars, but the product in this problem is a reducing sugar.
Lactose and maltose are reducing disaccharides, but sucrose is a nonreducing disaccharide. Explain.
