Ch.5 - Periodicity & Electronic Structure of Atoms

McMurry8th EditionChemistryISBN: 9781292336145Not the one you use?Change textbook

McMurry 8th Edition

Ch.5 - Periodicity & Electronic Structure of Atoms

Problem 7

Chapter 5, Problem 7

Which arrow in the energy diagram for an atom represents the absorption of light with the shortest wavelength? (LO 5.7)

Verified step by step guidance

Identify the energy levels (n) involved in each transition shown by the arrows in the diagram.

Recall that the energy difference between levels is given by the formula: \( \Delta E = E_f - E_i \), where \( E_f \) is the final energy level and \( E_i \) is the initial energy level.

Understand that the absorption of light corresponds to an electron moving from a lower energy level to a higher energy level.

Recognize that the shortest wavelength corresponds to the highest energy transition, as energy and wavelength are inversely related by the equation: \( E = \frac{hc}{\lambda} \).

Determine which arrow represents the transition with the largest energy difference (\( \Delta E \)), as this will correspond to the absorption of light with the shortest wavelength.

Verified video answer for a similar problem:

This video solution was recommended by our tutors as helpful for the problem above.

Video duration:

57s

Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Energy Levels in Atoms

Atoms have quantized energy levels, represented by principal quantum numbers (n). Electrons can occupy these levels, and transitions between them involve the absorption or emission of energy, typically in the form of light. The greater the difference in energy between levels, the higher the energy (and shorter the wavelength) of the absorbed or emitted light.

Wavelength and Energy Relationship

The energy of a photon is inversely related to its wavelength, described by the equation E = hc/λ, where E is energy, h is Planck's constant, c is the speed of light, and λ is the wavelength. Therefore, shorter wavelengths correspond to higher energy photons. This relationship is crucial for understanding which transitions in an energy diagram correspond to the absorption of light with the shortest wavelength.

Bohr Model of the Atom

The Bohr model describes the behavior of electrons in hydrogen-like atoms, where electrons orbit the nucleus in defined energy levels. When an electron absorbs energy, it can move to a higher energy level, which is depicted in energy diagrams with arrows indicating the direction of the transition. The arrows' lengths and positions reflect the energy differences between levels, helping to identify which transition corresponds to the absorption of light with the shortest wavelength.

Recommended video:

Guided course

02:43

Bohr Model of the Atom

Related Practice

Textbook Question

Calculate the wavelength in nm of the light emitted when an electron makes a transition from an orbital in n = 5 to an orbital in n = 2 in the hydrogen atom. (LO 5.8)(a) 2.31 * 10-3 nm (b) 4.34 * 10-2 nm (c) 231 nm(d) 434 nm

Textbook Question

What are the possible values of n, l, and ml for an electron in a 5p orbital? (LO 5.12)

views

Textbook Question

What are the possible values of n, l, and ml for the orbital shown? (LO 5.13)

Textbook Question

What is the energy (in kJ) of one mole of photons of ultraviolet light with a wavelength of 85 nm? (LO 5.3)(a) 1.4 * 10-6 kJ(b) 1.4 * 103 kJ(c) 2.4 * 1014 kJ(d) 2.4 * 10-15 kJ

views

Textbook Question

When a copper salt such as Cu(NO3)2 is burned in a flame, a blue-green color is emitted. Which figure represents the emission spectrum for the element copper? (LO 5.6)? (a)

(b)

(c)

(d)

views

Textbook Question

Which type of electromagnetic radiation will cause the greatest number of electrons to be ejected from zinc metal with a work function of 350 kJ/mol? (LO 5.4, 5.5)(a) Dim light with a wavelength of 320 nm (b) Dim light with a wavelength of 360 nm (c) Bright light with a wavelength of 360 nm (d) Bright light with a wavelength of 375 nm