A solution of sodium acetate (NaCH3COO) has a pH of 9.70. What is the molarity of the solution?

Name: Chemistry: The Central Science
Author: Brown
ISBN: 9780137542970

Verified step by step guidance

Step 1: Recognize that sodium acetate (NaCH3COO) is a salt that can hydrolyze in water to form acetic acid (CH3COOH) and hydroxide ions (OH^-), which makes the solution basic.

Step 2: Use the given pH to find the pOH of the solution. Recall that pH + pOH = 14, so pOH = 14 - pH.

Step 3: Calculate the hydroxide ion concentration [OH^-] using the formula [OH^-] = 10^{-pOH}.

Step 4: Write the hydrolysis equation for sodium acetate: CH3COO^- + H2O \(\rightleftharpoons\) CH3COOH + OH^-. Use the equilibrium expression K_b = \(\frac{[CH3COOH][OH^-]}{[CH3COO^-]}\) to relate the concentrations.

Step 5: Use the known value of K_w (1.0 \(\times\) 10^{-14}) and the K_a of acetic acid to find K_b for acetate ion: K_b = \(\frac{K_w}{K_a}\). Then, solve for the initial concentration of CH3COO^- using the equilibrium expression and the calculated [OH^-].

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Buffer Solutions

A buffer solution is a system that resists changes in pH upon the addition of small amounts of acid or base. Sodium acetate, being the salt of a weak acid (acetic acid) and a strong base (sodium hydroxide), acts as a buffer. This property is crucial for understanding how the pH of the solution can remain stable despite the presence of weak acids or bases.

pH and pKa Relationship

The pH of a solution is a measure of its acidity or basicity, defined as the negative logarithm of the hydrogen ion concentration. The pKa is the negative logarithm of the acid dissociation constant (Ka) and indicates the strength of an acid. In buffer solutions, the Henderson-Hasselbalch equation relates pH, pKa, and the ratio of the concentrations of the conjugate base and acid, which is essential for calculating molarity.

Molarity Calculation

Molarity is defined as the number of moles of solute per liter of solution. To find the molarity of sodium acetate in the solution, one can use the pH to determine the concentration of acetate ions and apply the Henderson-Hasselbalch equation. This calculation is fundamental in determining how much solute is present in a given volume of solution, which is key to answering the question.

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Pyridinium bromide 1C5H5NHBr2 is a strong electrolyte that dissociates completely into C5H5NH+ and Br-. An aqueous solution of pyridinium bromide has a pH of 2.95. (b) Using Appendix D, calculate the Ka for pyridinium bromide.

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Textbook Question

Pyridinium bromide 1C5H5NHBr2 is a strong electrolyte that dissociates completely into C5H5NH+ and Br-. An aqueous solution of pyridinium bromide has a pH of 2.95. (a) Write out the reaction that leads to this acidic pH.