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Terms in this set (15)
What is the general order for naming coordination compounds?
The metal cation is written before the nonmetal anion, and the complex ion is named before the counter ion.
When do you use Roman numerals in naming coordination compounds?
Roman numerals are used for transition metals with more than one possible charge, except for zinc (+2), cadmium (+2), and silver (+1), which do not require them.
How are neutral and anionic ligands ordered when naming a complex ion?
Neutral ligands are named before anionic ligands within the complex ion.
How are ligands listed within the name of a complex ion?
Ligands are named in alphabetical order, ignoring numerical prefixes like di-, tri-, etc.
What suffix is added to anionic ligands when naming coordination compounds?
The 'ide' ending is dropped and replaced with 'o' (e.g., chloride becomes chloro).
How is water named as a ligand in coordination compounds?
Water is named 'aqua' when it acts as a ligand.
What is the ligand name for NH3 in coordination compounds?
NH3 is named 'ammine' as a ligand.
What is the ligand name for CO in coordination compounds?
CO is named 'carbonyl' as a ligand.
How do you indicate the number of each ligand in a complex ion?
Numerical prefixes such as di-, tri-, tetra-, penta-, and hexa- are used to show the number of each ligand.
What change is made to the metal name if the complex ion is an anion?
The metal name is modified to its Latin root and the suffix '-ate' is added (e.g., iron becomes ferrate).
How is the charge of the central metal ion determined in a complex?
The charge is calculated by considering the charges of the ligands and counter ions, treating it like a math problem to solve for the metal's charge.
Where are brackets used in the formula of coordination compounds?
Brackets are used to enclose the entire complex ion in the formula.
How is a counter ion named if it is a nonmetal?
The counter ion is named with the suffix '-ide' (e.g., bromide for Br-).
What is the only place a space should appear in the name of a coordination compound?
A space appears only between the cation and the anion portions of the compound's name.
Why is it important to know the rules for naming coordination compounds?
Knowing the rules is essential because you may be asked to name a compound from its formula or write the formula from its name.